When sufficient voltage is applied to the chip across the leads of the LED, electrons can move easily in only one direction across the junction between the p and n regions. In the p region there are many more positive than negative charges. In the n region the electrons are more numerous than the positive electric charges. When a voltage is applied and the current starts to flow, electrons in the n region have sufficient energy to move across the junction into the p region. Once in the p region the electrons are immediately attracted to the positive charges due to the mutual Coulomb forces of attraction between opposite electric charges. When an electron moves sufficiently close to a positive charge in the p region, the two charges "re-combine".

Each time an electron recombines with a positive charge, electric potential energy is converted into electromagnetic energy. For each recombination of a negative and a positive charge, a quantum of electromagnetic energy is emitted in the form of a photon of light with a frequency characteristic of the semi-conductor material (usually a combination of the chemical elements gallium, arsenic and phosphorus). Only photons in a very narrow frequency range can be emitted by any material. LED's that emit different colors are made of different semi-conductor materials, and require different energies to light them.